Publications D’Elboux Bernardino, N.; Brown-Xu, S. E., Gustafson, T. L.; & Araujo de Faria, D. L. “Time Resolved Spectroscopy of Indigo and of a Maya Blue Simulant,” J. Phys. Chem. C, 2016, 120 (38), pp 21905–21914 Chisholm, Malcolm H.; Gustafson, Terry L.; Kender, William T.; Spilker, Thomas F.; Young, Philip J. “Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Ditungsten Quadruple Bonds,” Inorg. Chem. 2015 54(19), 9438–9446. Chisholm, Malcolm H.; Durr, Christopher B.; Gustafson, Terry L.; Kender, William T.; Spilker, Thomas F.; Young, Philip J. “Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Mo2 Quadruple Bonds: Suppression of the Photochemical Enol-to-Keto Transformation,” J. Am. Chem. Soc. 2015 137(15), 5155–5162. Brown-Xu, Samantha E.; Chisholm, Malcolm H.; Durr, Christopher B.; Gustafson, Terry L.; Spilker, Thomas F. “Photophysical Properties of cis-Mo2 Quadruply Bonded Complexes and Observation of Photoinduced Electron Transfer to Titanium Dioxide,” J. Am. Chem. Soc. 2014 136(32), 11428-11435. Brown-Xu, S. E.; Chisholm, M. H.; Durr, C. B.; Gustafson, T. L.; Spilker, T. F. “Coordination of N,N-Chelated Re(CO)3Cl Units Across a Mo2 Quadruple Bond: Synthesis, Characterization, and Photophysical Properties of a Re-Mo2-Re Triad and Its Component Pieces,” J. Phys. Chem. A 2013 117, 5997-6006. Chisholm, M. H.; Gustafson, T. L.; Turro, C. “Photophysical Properties of MM Quadruply Bonded Complexes Supported by Carboxylate Ligands, MM = Mo2, MoW, or W2,” Accounts of chemical research 2013 46, 529-538. Alberding, B. G.; Brown-Xu, S. E.; Chisholm, M. H.; Epstein, A. J.; Gustafson, T. L.; Lewis, S. A.; Min, Y. “Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide,” Dalton Trans. 2013 42, 15, 5275-5280. Brown-Xu, S. E.; Chisholm, M. H.; Durr, C. B.; Gustafson, T. L.; Naseri, V.; Spilker, T. F. “Electronic Structure and Excited-State Dynamics of the Molecular Triads: trans-M2(TiPB)2[O2CC6H5-η6-Cr(CO)3]2, Where M = Mo or W, and TiPB=2,4,6-triisopropylbenzoate,” J. Am. Chem. Soc. 2012 134, 51, 20820-20826. Hauser, A. J.; Soliz, J. R.; Dixit, M.; Williams, R. E. A.; Susner, M. A.; Peters, B.; Mier, L. M.; Gustafson, T. L.; Sumption, M. D.; Fraser, H. L.; Woodward, P. M.; Yang, F. Y. “Fully ordered Sr2CrReO6 epitaxial films: A high-temperature ferrimagnetic semiconductor,” Phys. Rev. 2012 85, 16, 161-201. Alberding, B. G.; Chisholm, M. H.; Gustafson, T. L. “Detection of the Singlet and Triplet MM δδ* States in Quadruply Bonded Dimetal Tetracarboxylates (M = Mo, W) by Time-Resolved Infrared Spectroscopy,” Inorg. Chem. 2012 21, 1, 491-498. Alberding, B. G.; Brown-Xu, S. E.; Chisholm, M. H.; Gustafson, T. L.; Reed, C. R.; Naseri, V. “Photophysical properties of MM quadruply bonded complexes (M = Mo, W) supported by carboxylate ligands: charge delocalization and dynamics in S1 and T1states,” Dalton Trans. 2012 41, 42, 13097-13104. Alberding, B. G.; Brown-Xu, S. E.; Chisholm, M. H.; Gallucci, J. C.; Gustafson, T. L.; Naseri, V.; Reed, C. R.; Turro, C. “Molecular and electronic structures and photophysical properties of quadruply bonded dimetal complexes (M = Mo or W) supported bytrans-arylethynylcarboxylate ligands where aryl = p-tolyl or 9-anthrancenyl,” Dalton Trans. 2012 41, 39, 12270-12281. Brown-Xu, S. E.; Chisholm, M. H.; Gallucci, J. C.; Ghosh, Y.; Gustafson, T. L.; Reed, C. R. “Furan- and selenophene-2-carboxylato derivatives of dimolybdenum and ditungsten (M M): a comparison of their chemical and photophysical properties,”Dalton Trans. 2012 41, 8, 2257-2263 2012. Wilfong, E. M.; Kogiso, Y.; Muthukrishnan, S.; Kowatz, T.; Du, Y.; Bowie, A.; Naismith, J. H.; Hadad, C. M.; Toone, E. J.; Gustafson, T. L. “A Multidisciplinary Approach to Probing Enthalpy-Entropy Compensation and the Interfacial Mobility Model,” J. Am. Chem. Soc. 2011 133, 30, 11515-11523. Alberding, B. G.; Chisholm, M. H.; Gallucci, J. C.; Ghosh, Y.; Gustafson, T. L. “Electron delocalization in the S1 and T1 metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes,” Proc. Natl. Acad. Sci. USA 2011 108, 20, 8152-8156. Alberding, B. G.; Chisholm, M. H.; Gustafson, T. L.; Liu, Y.; Reed, C. R.; Turro, C. “Photophysical Studies of trans-Bis(phenylethynyldiisopropylamidinato)bis(acetato)dimetal Complexes Involving MM Quadruple Bonds Where M = Mo or W,” J. Phys. Chem. A 2010 144, 48, 12675-12681. Alberding, B. G.; Barybin, M. V.; Chisholm, M. H.; Gustafson, T. L.; Reed, C. R.; Robinson, R. E.; Patmore, N. J.; Singh, N.; Turro, C. “Molecular, electronic structure and spectroscopic properties of MM quadruply bonded units supported by trans-6-carboethoxy-2-carboxylatoazulene ligands,” Dalton Trans. 2010 39, 1979-1984. Alberding, B. G.; Chisholm, M. H.; Chou, Y. H.; Gallucci, J. C.; Ghosh, Y.; Gustafson, T. L.; Patmore, N. J.; Reed, C. R.; Turro, C. “Quadruply Bonded Dimetal Units Supported by 2,4,6-Triisopropylbenzoates MM(TiPB)4 (MM = Mo2, MoW, and W2): Preparation and Photophysical Properties,” Inorg. Chem. 2009 48, 4394-4399. Alberding, B. G.; Chisholm, M. H.; Gustafson, T. L.; Reed, C. R.; Singh, N.; Turro, C. “[Bis(trispivalatodimolybdenum (II))-μ-bis(4′-carboxylato-2,2′:6′,2”-terpyridine) ruthenium (II)] (2+) Tetrafluoroborate: Photophysical Studies,” J. Cluster Sci. 200920, 307-317. Alberding, B. G.; Chisholm, M. H.; Ghosh, Y.; Gustafson, T. L.; Liu, Y.; Turro, C.; “Sexithiophenes Mediated by MM Quadruple Bonds:; MM = Mo2, MoW and W2,” Inorg. Chem. 2009 48, 8536-8543. Alberding, B. G..; Chisholm, M. H.; Chou, Y.-H.; Ghosh, Y.; Gustafson, T. L.; Liu, Y.; Turro, C. “2-Thienylcarboxylato and 2-Thienylthiocarboxylato Ligands Bonded to MM Quadruple Bonds (M = Mo or W): A Comparison of Ground State, Spectroscopic and Photoexcited State Properties,” Inorg. Chem. 2009 48, 11187-11195. Chisholm, M. H.; Chou, P.-T.; Chou, Y.-H.; Ghosh, Y.; Gustafson. T. L.; Ho, M.-L. “Preparations and Photophysical Properties of Fused and Non-Fused Thienyl Bridged MM (M = Mo or W) Quadruply Bonded Complexes,” Inorg. Chem. 2008 47, 3415-3425. Wang, J.; Kubicki, J.; Gustafson, T. L.; Platz, M. S. “The Dynamics of Carbene Solvation:; An Ultrafast Study of p-Biphenylyltrifluoromethylcarbene,” J. Am. Chem. Soc. 2008 130, 2304-2313. Burdzinski, G. T.; Wang, J.; Gustafson, T. L.; Platz, M. S. “Study of Concerted and Sequential Photochemical Wolff Rearrangement by Femtosecond UV-Vis and IR Spectroscopy,” J. Am. Chem. Soc. 2008 130, 3746-3747. Wang, J.; Burdzinski, G. T.; Kubicki, J.; Gustafson, T. L.; Platz, M. S. “Ultrafast Carbene – Carbene Isomerization,” J. Am. Chem. Soc. 2008 130, 5418-5419. Hauser, A. J.; Zhang, J.; Mier, L. M.; Ricciardo, R. A.; Woodward, P. M.; Gustafson, T. L.; Brillson, L. J.; Yang, F. Y. “Characterization of Electronic Structure and Defect States of Thin Epitaxial BiFeO3 Films by UV-visible Absorption and Cathodoluminescence Spectroscopies,” Appl. Phys. Lett. 2008 92, 222901-1-3. Burdzinski, G. T.; Chisholm, M. H.; Chou, P.-T.; Chou, Y.-H.;Feil, F.;; Gallucci, J. C.; Ghosh, Y.; Gustafson, T. L.; Ho, M.-L.; Liu, Y.; Ramnauth, R.; Turro, C. “The Remarkable Influence of M2δ to Thienyl π Conjugation in Oligothiophenes Incorporating MM Quadruply Bonds,” Proc. Natl. Acad. Sci. USA 2008 105, 15247-15252. Wang, J.; Burdzinski, G. T.; Gustafson, T. L.; Platz, M. S. “Ultrafast Study of p-Biphenylyldiazoethane. The Chemistry of the Diazo Excited State and the Relaxed Carbene,” J. Am. Chem. Soc. 129, 2597-2606 2007. Wang, J.; Kubicki, J.; Hilinski, E.; Gustafson, T. L.; Platz, M. S. “Ultrafast Study of 9-Diazofluorene: Direct Observation of the Excited Singlet Carbene,” J. Am. Chem. Soc. 2007 129, 13683-13690. Wang, J.; Kubicki, J.; Burdzinski, G.T.; Hackett, J.C.; Gustafson, T.L.; Hadad, C.M.; Platz, M.S. “Early Events in the Photochemistry of 2-Naphthyl Azide from Femtosecond UV/Vis Spectroscopy and Quantum Chemical Calculations. Direct Observation of a Very Short-lived Singlet Nitrene,” J. Org. Chem., 2007 72, 7581-7586. Wang, J.; Burdzinski, G.T.; Gustafson, T.L.; Platz, M.S. “Ultrafast Study of p-Biphenylyldiazoethane. The Chemistry of the Diazo Excited State and the Relaxed Carbene,” J. Am. Chem. Soc. 2007 129, 2597-2606. Burdzinski, G.T.; Middleton, C.T.; Gustafson, T.L.; Platz, M.S. “Solution Phase Isomerization of Vibrationally Excited Singlet Nitrenes to Vibrationally Excited 1,2-Didehydroazepine,” J. Am. Chem. Soc. 2006 128, 14804-14805. Gabriel, C.J.; DeMatteo, M.P.; Paul, N.M.; Takaya, T.; Gustafson, T.L.; Hadad, C.M.; Parquette, J.R. “A New Class of Intramolecularly Hydrogen-bonded Dendrons Based on a 2-Methoxy-isophthalamide Repeat Unit,” J. Org. Chem. 2006 71, 9035-9044. Wang, J. Burdzinski, G.T.; Gustafson, T.L; Platz, M.S. “Ultrafast Study of para-Biphenyldiazomethane and para-Biphenylcarbene,”J. Org. Chem. 2006 71, 6221-6228. Burdzinski, G.T.; Hackett, J.C.; Wang, J.; Gustafson, T.L.; Hadad, C.M.; Platz, M.S. “Early Events in the Photochemistry of Aryl Azides from Femtosecond UV/Vis Spectroscopy and Quantum Chemical Calculations,” J. Am. Chem. Soc. 2006 128, 13402-13411. Burdzinski, G.T.; Ramnauth, R.; Chisholm, M.H.; Gustafson, T.L. “The Direct Observation of a 1MLCT State by Ultrafast Transient Absorption Spectroscopy in Mo2 (O2C-9-anthracene)4,” J. Am. Chem. Soc. 2006 128, 6776-6777.