{"id":18,"date":"2015-04-15T14:30:55","date_gmt":"2015-04-15T18:30:55","guid":{"rendered":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/?page_id=18"},"modified":"2017-03-27T10:00:53","modified_gmt":"2017-03-27T14:00:53","slug":"publications","status":"publish","type":"page","link":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
Original Publications – All<\/span><\/td>\n<\/tr>\n<\/thead>\n
\n
Number<\/span><\/div>\n<\/td>\n
Title, Authors<\/span><\/p>\n
\n

Journal, Year, Volume, Pages<\/span><\/td>\n<\/tr>\n

\n
104<\/span><\/div>\n<\/td>\n
“Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene”, Timsina, Y. T.; Biswas, S.; RajanBabu, T. V.\u00a0\u00a0\u00a0\u00a0 http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja501979g<\/a><\/span><\/p>\n
\n

J. Am. Chem. Soc. 2014, 136, 6215-6218.
\n<\/span><\/td>\n<\/tr>\n

\n
103<\/span><\/div>\n<\/td>\n
“Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vinylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes”, Biswas, S.; Zhang, A.; Raya, B.; RajanBabu, T. V.<\/span><\/p>\n
\n

Adv. Synth. Catal. 2014, , (In Press)<\/span><\/td>\n<\/tr>\n

\n
102<\/span><\/div>\n<\/td>\n
“Bimetallic Catalysis in the Highly Stereoselective Ring-Opening Reactions of Aziridines”, Wu, B.; Gallucci, J. C.; Parquette, J. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

Chem. Sci. 2014, 5, 1102-1117.<\/span><\/td>\n<\/tr>\n

\n
101<\/span><\/div>\n<\/td>\n
“Highly Efficient Catalytic Dimerization of Styrenes via Cationic Palladium(II) Complexes”, Choi, J. H.; Kwon, J. K.; RajanBabu, T. V.; Lim, H. J.<\/span><\/p>\n
\n

Adv. Synth. Catal. 2013, 355, 3633-3638.<\/span><\/td>\n<\/tr>\n

\n
100<\/span><\/div>\n<\/td>\n
“Conformation and reactivity in dibenzocyclooctadienes (DBCOD). A general approach to the total synthesis of fully substituted DBCOD lignans via borostannylative cyclization of ?,?-diynes”, Gong, W.; RajanBabu, T. V.<\/span><\/p>\n
\n

Chem. Sci. 2013, 4, 3979-3985.<\/span><\/td>\n<\/tr>\n

\n
99<\/span><\/div>\n<\/td>\n
“Asymmetric Hydrovinylation of 1-Vinylcycloalkenes. Reagent Control of Regio- and Stereoselectivity”, Page, J. P.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2012, 134, 6556-6559.<\/span><\/td>\n

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98<\/span><\/div>\n<\/td>\n
“Asymmetric Hydrovinylation of Vinylindoles. A Facile Route to Cyclopenta[g]indole Natural Products (+)-cis-Trikentrin A and (+)-cis-Trikentrin B”, Liu, W.; Lim, H. J.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2012, 134, 5496-5499.<\/span><\/td>\n

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97<\/span><\/div>\n<\/td>\n
“On the stereochemistry of acetylide additions to highly functionalized biphenylcarbaldehydes and multi-component cyclization of 1,n-diynes. syntheses of dibenzocyclooctadiene lignans.”, Gong, W.; Singidi, R. R.; Gallucci, J. C.; RajanBabu, T. V.<\/span><\/p>\n
\n

Chem. Sci. 2012, 3, 1221-1230.<\/span><\/td>\n

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96<\/span><\/div>\n<\/td>\n
“Ethylene in Organic Synthesis: A New Route to Anticholenergic Pyrrolidinoindolines, and Other Molecules with All Carbon-Quaternary Centers via Asymmetric Hydrovinylation”, Lim, H. J.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2011, 13, 6596-6599.<\/span><\/td>\n

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95<\/span><\/div>\n<\/td>\n
“Ethylene in Organic Synthesis. Repetitive Hydrovinylation of Alkenes for Highly Enantioselective Syntheses of Pseudopterosins”, Mans, D. J.; Cox, G. A.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2011, 133, 5776-5779.<\/span><\/td>\n

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94<\/span><\/div>\n<\/td>\n
“Reactivity and Selectivity in Hydrovinylation of Strained Alkenes”, Liu, W.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2010, 75, 7636-7643.<\/span><\/td>\n

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93<\/span><\/div>\n<\/td>\n
“Stereoselective Cyclization of Functionalized 1,n-Diynes Mediated by [X-Y]- Reagents [X-Y = R3Si-SnR’3 or (R2N)2B-SnR’3]. Synthesis and Properties of Atropisomeric 1,3-Dienes”, Singidi, R. R.; Kutney, A. M.; Gallucci, J. C.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2010, 132, 13078-13087.<\/span><\/td>\n

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92<\/span><\/div>\n<\/td>\n
“Borostannylation of Alkynes and Enynes. Scope and Limitations of the Reaction and Utility of the Adducts”, Singidi, R. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2010, 12, 2622-2625.<\/span><\/td>\n

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91<\/span><\/div>\n<\/td>\n
“Annulated Diketopiperazines from Dipeptides or Schollkopf Reagents via Tandem Cyclization-N-Arylation”, Lim, H. J.; Gallucci, J. C.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2010, 12, 2162-2165.<\/span><\/td>\n

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90<\/span><\/div>\n<\/td>\n
“Mechanism and Stereoselection in a Y-Catalyzed Transacylation Reaction. A Computational Modeling Study”, Sanan, T.T; RajanBabu, T. V.; Hadad, C. M.<\/span><\/p>\n
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J. Org. Chem. 2010, 75, 2369-2381.<\/span><\/td>\n

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89<\/span><\/div>\n<\/td>\n
“Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes”, Sharma, R. S.; RajanBabu, T. V.<\/span><\/p>\n
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J. Am. Chem. Soc. 2010, 132, 3295-3297.<\/span><\/td>\n

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88<\/span><\/div>\n<\/td>\n
“A Low Pressure Vinylation of Aryl and Vinyl Halides via Mizoroki-Heck Reactions Using Ethylene”, Smith, C. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

Tetrahedron 2010, 66, 1102-1110.<\/span><\/td>\n

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87<\/span><\/div>\n<\/td>\n
“Regiodivergent Ring Opening of Chiral Aziridines”, Wu, B.; Parquette, J. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

Science 2009, 326, 1662.<\/span><\/td>\n

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86<\/span><\/div>\n<\/td>\n
“Seleniranium Ion-Triggered Reactions:New Aspects of Friedel-Crafts and N-Detosylative Cyclizations”, Lim, H. J.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2009, 11, 2924-2927.<\/span><\/td>\n

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85<\/span><\/div>\n<\/td>\n
“Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers”, Smith, C. R.; Lim, H. J.; Zhang, A.; RajanBabu, T. V.<\/span><\/p>\n
\n

Synthesis 2009, 12, 2089-2100.<\/span><\/td>\n

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84<\/span><\/div>\n<\/td>\n
“Catalytic Asymmetric Synthesis Using Feedstocks. An Enantioselective Route to 2-Arylpropionic Acids and 2-Arylethyl Amines via Hydrovinylation of Vinylarenes”, Smith, C. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2009, 74, 3066-3072.<\/span><\/td>\n

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83<\/span><\/div>\n<\/td>\n
“Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes”, Lim, H. J.; Smith, C. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2009, 74, 4565-4572.<\/span><\/td>\n

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82<\/span><\/div>\n<\/td>\n
“A Theoretical Investigation of the Mechanism of Hydrovinylation Reaction”, Joseph, J.; RajanBabu, T. V.; Jemmis, E. D.<\/span><\/p>\n
\n

Organometallics 2009, 28, 3552-3566.<\/span><\/td>\n

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81<\/span><\/div>\n<\/td>\n
“Enantioselective Desymmetrization of meso-Aziridines by TMSN3 and TMSCN Catalyzed by Discrete Yttrium Complexes”, Wu, B.; Gallucci, J. C.; Parquette, J. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

Angew. Chem. Int. Ed. 2009, 48, 1126-1129.<\/span><\/td>\n

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80<\/span><\/div>\n<\/td>\n
“In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction. The<\/span>
\n Hydrovinylation of Alkenes”, RajanBabu, T. V.; Nomura, N.; Jin, J.; Nandi, M.; Park, H.; Ramaiah, K.; Zhang, A.; Saha, B.; Mans, D.; Smith, C. R.; Lim, H.<\/span><\/p>\n
\n

Synlett 2009, 21, 853-885.<\/span><\/td>\n

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79<\/span><\/div>\n<\/td>\n
“Catalyzed Cyclizations Leading to Enrichment of Functionality and Chirality. A General Approach to Dibenzocyclooctadiene Lignans from \u03b1,\u03c9-Diynes”, Singidi, R. R.; RajanBabu, T. V<\/span><\/p>\n
\n

Org. Lett. 2008, 10, 3351-3354.<\/span><\/td>\n

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78<\/span><\/div>\n<\/td>\n
“Conformationally Driven Asymmetric Induction in a Catalytic Dendrimer”, Yu, J.; RajanBabu, T. V.; Parquette, J. R.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2008, 130, 7845-7847.<\/span><\/td>\n

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77<\/span><\/div>\n<\/td>\n
“Efficient, Selective and Green: Catalyst Tuning for Highly Enantioselective Reactions of Ethylene”, Smith, C. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2008, 10, 1657-1659.<\/span><\/td>\n

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76<\/span><\/div>\n<\/td>\n
“Ligand Tuning in Asymmetric Hydrovinylation of 1,3-Dienes. A Stereoselective Route to either Steroid-C20(S) or -C20(R) Derivatives”, Saha, B.; Smith, C. R.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2008, 130, 9000-9005.<\/span><\/td>\n

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75<\/span><\/div>\n<\/td>\n
“(R)-3-Methyl-3-phenyl-1-pentene via Catalytic Asymmetric Hydrovinylation”, Smith, C. R.; Zhang, A.; Mans, D.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Synth. 2008, 85, 238-247.<\/span><\/td>\n

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74<\/span><\/div>\n<\/td>\n
“(R)-2,2\ufffd-Binaphthoyl-(S,S)-Di(1-phenylethyl) Aminophosphine. Scalable Protocols for the Synthesis of Phosphoramidite (Feringa) Ligands”, Smith, C. R.; Mans, D.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Synth. 2008, 85, 248-266.<\/span><\/td>\n

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73<\/span><\/div>\n<\/td>\n
“Exceptionally Active Yttrium-Salen Complexes for the Catalyzed Ring Opening of Epoxides by TMSCN and TMSN3<\/sub>“, Saha, B.; Lin, M- H.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2007, 72, 8648-8655.<\/span><\/td>\n

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72<\/span><\/div>\n<\/td>\n
“Syntheses and Applications of 2-Phosphino-2′-alkoxy-1,1′-binaphthyl Ligands. Development of a Working Model for Asymmetric Induction in Hydrovinylation Reactions”, Saha, B.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2007, 72, 2357-2363.<\/span><\/td>\n

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71<\/span><\/div>\n<\/td>\n
“Nickel(0)-Catalyzed Asymmetric Hydrocyanation of 1,3-Dienes”, Saha, B.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2006, 8, 4657-4659.<\/span><\/td>\n

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70<\/span><\/div>\n<\/td>\n
“All Carbon Quaternary Centers via Asymmetric Hydrovinylation. New Approaches to the Exocyclic Side Chain Stereochemistry Problem”, Zhang, A.; RajanBabu, T. V.<\/span><\/p>\n
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J. Am. Chem. Soc. 2006, 128, 5620-5621.<\/span><\/td>\n

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69<\/span><\/div>\n<\/td>\n
“Hydrovinylation of 1,3-Dienes: A New Protocol, an Asymmetric Variation, and a Potential Solution to the Exocyclic Side Chain Stereochemistry Problem”, Zhang, A.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2006, 128, 54-55.<\/span><\/td>\n

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68<\/span><\/div>\n<\/td>\n
“Tunable Phosphinite, Phosphite and Phosphoramidite Ligands for Asymmetric Hydrovinylation Reaction”, Park, H.; Kumareswaran, R.; RajanBabu, T. V.<\/span><\/p>\n
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Tetrahedron 2005, 61, 6352-6367.<\/span><\/td>\n

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67<\/span><\/div>\n<\/td>\n
“Silylstannylation of Highly Functionalized Acetylenes. Synthesis of Precursors for Annulations via Radical or Heck Reactions”, Apte, S.; Radetich, B.; Shin, S.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2004, 6(22), 4053-4056.<\/span><\/td>\n

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66<\/span><\/div>\n<\/td>\n
“Tuning the Acceptors in Catalyzed Cyclizations Initiated by Allenes. Silylstannylation\/Cyclization of Allene-Aldehydes for Synthesis of Indolizidine including 223A Congeners”, Kumareswaran, R.; Gallucci, J.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2004, 69(26), 9151-9158.<\/span><\/td>\n

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65<\/span><\/div>\n<\/td>\n
“Chiral Benzyl Centers through Asymmetric Catalysis. A Three Step Synthesis of (R)-(-)- \u03b1-Curcumene”, Zhang, A.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2004, 6, 3159-3162.<\/span><\/td>\n

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64<\/span><\/div>\n<\/td>\n
“Silylstannylation of Allenes and Silylstannylation-Cyclization of Allenynes. Synthesis of Highly Functionalized Allyl Stannanes, Carbocyclic and Heterocyclic Compounds”, Kumareswaran, R.; Shin, S.; Gallou, I.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2004, 69, 7157-7170.<\/span><\/td>\n

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63<\/span><\/div>\n<\/td>\n
“Homogeneous Two-Component Polycondensation without Strict Stoichiometric Balance via the Tsuji-Trost Reaction: Remote Control of Two Reaction Sites by Catalysis”, Nomura, N.; Tsurugi, K.; RajanBabu, T. V. Kondo, T.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2004, 126, 5354-5355.<\/span><\/td>\n

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62<\/span><\/div>\n<\/td>\n
“Fine-tuning Monophosphine Ligands for Enhanced Enantioselectivity. Influence of Chiral Hemilabile Pendant Groups”, Zhang, A.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2004, 6(9), 1515-1517.<\/span><\/td>\n

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61<\/span><\/div>\n<\/td>\n
“Heterodimerization of Olefins 1. Hydrovinylation Reactions of Olefins That Are Amenable to Asymmetric Catalysis”, RajanBabu, T. V.; Nomura, N.; Jin, J.; Nandi, M.; Park, H.; Sun, X.<\/span><\/p>\n
\n

J. Org. Chem. 2003, 68, 8431-8446.<\/span><\/td>\n

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60<\/span><\/div>\n<\/td>\n
“Hydrovinylation of Norbornene. Ligand Dependent Selectivity and Asymmetric Variations”, Kumareswaran, R.; Nandi, N.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2003, 5, 4345-4348.<\/span><\/td>\n

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59<\/span><\/div>\n<\/td>\n
“Axial Chirality in 1,4-Disubstituted (ZZ)-1,3-Dienes. Surprisingly Low Activation Barriers for Enantiomerization in Synthetically Useful Fluxional Molecules”, Warren, S.; Chow, A.; Fraenkel, G.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2003, 125, 15402-15410.<\/span><\/td>\n

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58<\/span><\/div>\n<\/td>\n
“Stereochemical Control in Radical Cyclization Routes to N-Glycosides: Role of Protecting Groups and of the Configuration (E vs. Z) of the Acceptors”, Rhee, J. U.; Bliss, B. I.; RajanBabu, T. V.<\/span><\/p>\n
\n

Tetrahedron Asymmetry 2003, 14(19), 2939-2959.<\/span><\/td>\n

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57<\/span><\/div>\n<\/td>\n
“Asymmetric Hydrovinylation Reaction”, RajanBabu, T. V.<\/span><\/p>\n
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Chem. Rev. 2003, 103(8), 2845-2860.<\/span><\/td>\n

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56<\/span><\/div>\n<\/td>\n
“A New Reaction Manifold for the Barton Radical Intermediates. Synthesis of N-Heterocyclic Furanosides and Pyranosides through the Formation of the C1-C2 Bond”, Rhee, J. U.; Bliss, B. I.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2003, 125, 1492-1493.<\/span><\/td>\n

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55<\/span><\/div>\n<\/td>\n
“Ligand-assisted Rate Acceleration in Transacylation by a Yttrium-Salen Complex. Demonstration of a Conceptually New Strategy for Metal-catalyzed Kinetic Resolution of Alcohols”, Lin, M. H.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2002, 4, 1607-1610.<\/span><\/td>\n

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54<\/span><\/div>\n<\/td>\n
“Tunable Ligands for Asymmetric Catalysis. Readily Available Carbohydrate-derived Diarylphosphinites Induce High Selectivity in the Hydrovinylation of Styrene Derivatives”, Park, H.; RajanBabu,T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2002, 124, 734-735.<\/span><\/td>\n

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53<\/span><\/div>\n<\/td>\n
“Synthesis, Characterization and Applicability of Neutral, Polyhydroxy Phospholane Derivatives and Their Rhodium (I) Complexes for Reactions in Organic and Aqueous Media”, RajanBabu, T. V.; Yan, Y.; Shin, S.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2001, 123, 10207-10212.<\/span><\/td>\n

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52<\/span><\/div>\n<\/td>\n
“Regio- and Stereochemical Control in Bis-functionalization-Cyclization. Use of Alleneyne Precusors for Carbocyclic and Heterocyclic Synthesis”, Shin, S.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2001, 123, 8416-8417.<\/span><\/td>\n

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51<\/span><\/div>\n<\/td>\n
“Asymmetric Synthesis of Functionalized 1,2,3,4-Tetrahydroquinolines”, Gallou-Dagommer, I.; Gastaud, P.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2001, 3, 2053-2056.<\/span><\/td>\n

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50<\/span><\/div>\n<\/td>\n
“Water-Soluble Organometallic Catalysts from Carbohydrates. 2. A Strategy for the Preparation of Catalysts with Pendant Quaternary Ammonium Groups Using D-Salicin”, Yan, Y.-Y.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2001, 66, 3277-3283.<\/span><\/td>\n

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49<\/span><\/div>\n<\/td>\n
“First Demonstration of Helical Chirality in 1,4-Disubstituted (Z,Z)-1,3-Dienes. R3Si-SnR’3-mediated Cyclization of 1,6-Diynes”, Gr\u00e9au, S.; Radetich, B.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 2000, 122, 8579-8580.<\/span><\/td>\n

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48<\/span><\/div>\n<\/td>\n
“Ligand Substituent Effects on Asymmetric Induction. Effect of Structural Variations of the DIOP Ligand on the Rh-Catalyzed Asymmetric Hydrogenation of Enamides”, Yan, Y.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2000, 2, 4137-4140.<\/span><\/td>\n

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47<\/span><\/div>\n<\/td>\n
“Ligand Tuning in Asymmetric Catalysis: Mono- and Bis-Phospholanes for a Prototypical Pd-Catalyzed Asymmetric Allylation Reaction”, Yan, Y.-Y.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2000, 2, 199-202.<\/span><\/td>\n

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\n
46<\/span><\/div>\n<\/td>\n
“Heterodimerization of Propylene and Vinylarenes: Functional Group Compatibility in a Highly Efficient Ni-Catalyzed Carbon-Carbon Bond-Forming Reaction”, Jin, J.; RajanBabu, T. V.<\/span><\/p>\n
\n

Tetrahedron 2000, 56, 2145-2151.<\/span><\/td>\n

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\n
45<\/span><\/div>\n<\/td>\n
“Highly Flexible Synthetic Routes to Functionalized Phospholanes from Carbohydrates”, Yan, Y.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 2000, 65, 900-906.<\/span><\/td>\n

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\n
44<\/span><\/div>\n<\/td>\n
“Metal-Catalyzed Acyl Transfer Reactions of Enol Esters: Role of Y5(OiPr)13O as a Superb Transesterification Catalyst”, Lin. M. -H.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2000, 2, 997-1000.<\/span><\/td>\n

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\n
43<\/span><\/div>\n<\/td>\n
“First Chelated Chiral N-Heterocyclic bis-Carbene Complexes”, Clyne, D. S.; Jin, J.; Genest, Gallucci, J. C.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 2000, 2, 1125-1128.<\/span><\/td>\n

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\n
42<\/span><\/div>\n<\/td>\n
“Water-Soluble Organometallic Catalysts from Carbohydrates. 1. Diarylphosphinite-Rh Complexes”, Shin, S.; RajanBabu, T. V.<\/span><\/p>\n
\n

Org. Lett. 1999, 1, 1229-1232.<\/span><\/td>\n

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\n
41<\/span><\/div>\n<\/td>\n
“Synergistic Effects of Hemilabile Coordination and Counterions in Homogeneous Catalysis: New Tunable Monophosphine Ligands for Hydrovinylation Reactions”, Nandi, M.; Jin, J.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1999, 121, 9899-9900.<\/span><\/td>\n

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\n
40<\/span><\/div>\n<\/td>\n
“Substituent Effects of Ligands on Asymmetric Induction in a Prototypical Palladium-Catalyzed Allylation Reaction: Making Both Enantiomers of a Product in High Optical Purity Using the Same Source of Chirality”, Clyne, D. S.; Mermet-Bouvier, Y. C.; Nomura, N.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 1999, 64, 7601-7611.<\/span><\/td>\n

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\n
39<\/span><\/div>\n<\/td>\n
“Hydrovinylation and Related Reactions: New Protocols and Control Elements in Search of Greater Synthetic Efficiency and Selectivity”, RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M.<\/span><\/p>\n
\n

Chem. Eu. J. 1999, 5, 1963-1968.<\/span><\/td>\n

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\n
38<\/span><\/div>\n<\/td>\n
“Electronic Effects in Asymmetric Catalysis: Structural Studies of Precatalysts and Intermediates in Rh-Catalyzed Hydrogenation of Dimethyl Itaconate and Acetamidocinnamic Acid Derivatives Using C2-Symmetric Diarylphosphinite Ligands”, RajanBabu, T. V.; Radetich, B.; You, K. K.; Ayers, T. A.; Casalnuovo, A. L.; Calabrese, J. C.<\/span><\/p>\n
\n

J. Org. Chem. 1999, 64, 3429-3447.<\/span><\/td>\n

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\n
37<\/span><\/div>\n<\/td>\n
“Catalytic Cyclization of \u03b1,\u03c9-Dienes: A Versatile Protocol for the Synthesis of Functionalized Carbocylic and Heterocyclic Compounds”, Radetich, B.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1998, 120, 8007-8008.<\/span><\/td>\n

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\n
36<\/span><\/div>\n<\/td>\n
“The Hydrovinylation Reaction: A New Highly Selective Protocol Amenable to Asymmetric Catalysis”, Nomura, N.; Jin, J.; Park, H.; RajanBabu, T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1998, 120, 459-460.<\/span><\/td>\n

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\n
35<\/span><\/div>\n<\/td>\n
“Carbohydrate Phosphinites as Practical Ligands in Asymmetric Catalysis: Electronic Effects and Dependence of Back-bone Chirality in Rh-Catalyzed Asymmetric Hydrogenations. Synthesis of R- or S- Amino Acids Using Natural Sugars as Ligand Precursors”, RajanBabu, T. V.; Ayers, T. A.; Halliday, G. A.; You, K. K.; Calabrese, J. C.<\/span><\/p>\n
\n

J. Org. Chem. 1997, 62, 6012-6028.<\/span><\/td>\n

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\n
34<\/span><\/div>\n<\/td>\n
“Nickel-Catalyzed Asymmetric Allylation of Alkyl Grignard Reagents. Effect of Ligands, Leaving Groups and a Kinetic Resolution with a Hard Nucleophile”, Nomura, N.; RajanBabu, T. V.<\/span><\/p>\n
\n

Tetrahedron Lett. 1997, 38, 1713-1716.<\/span><\/td>\n

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\n
33<\/span><\/div>\n<\/td>\n
“Role of Electronic Asymmetry in the Design of New Ligands: The Asymmetric Hydrocyanation Reaction”, RajanBabu, T. V.; Casalnuovo, A. L.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1996, 118, 6325-6326.<\/span><\/td>\n

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\n
32<\/span><\/div>\n<\/td>\n
“Unprecedented Electronic and Steric Effects in Palladium-Catalyzed Asymmetric Allylation: Switching of Enantioselectivity with a Single Chiral Back-bone”, Nomura, N.; Mermet-Bouvier, Y. C.; RajanBabu, T. V.<\/span><\/p>\n
\n

Synlett. 1996, 8, 745-746.<\/span><\/td>\n

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\n
31<\/span><\/div>\n<\/td>\n
“Ligand Electronic Effects in Asymmetric Catalysis: Enhanced Enantioselectivity in Asymmetric Hydrocyanation of Vinylarenes”, Casalnuovo, A. L.; RajanBabu, T. V.; Ayers, T. A.; Warren, T.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1994, 116, 9869-9882.<\/span><\/td>\n

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\n
30<\/span><\/div>\n<\/td>\n
“Electronic Effects in Asymmetric Catalysis: Hydroformylation of Olefins”, RajanBabu, T. V.; Ayers, T. A.<\/span><\/p>\n
\n

Tetrahedron Lett. 1994, 35, 4295-4298.<\/span><\/td>\n

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\n
29<\/span><\/div>\n<\/td>\n
“Electronic Amplification of Selectivity in Rh-Catalyzed Hydrogenations: D-Glucose-Derived Ligands for the Synthesis of D- or L- Amino Acids”, RajanBabu, T. V.; Ayers, T. A.; Casalnuovo, A. L.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1994, 116, 4101-4102.<\/span><\/td>\n

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\n
28<\/span><\/div>\n<\/td>\n
“Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis”, RajanBabu, T. V.; Nugent, W. A.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1994, 116, 986-997.<\/span><\/td>\n

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\n
27<\/span><\/div>\n<\/td>\n
“Beyond Nature’s Chiral Pool: Enantioselective Catalysis in Industry”, Nugent, W. A.; RajanBabu, T. V.; Burk, M. J.<\/span><\/p>\n
\n

Science 1993, 259, 479-483.<\/span><\/td>\n

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\n
26<\/span><\/div>\n<\/td>\n
“Tailored Ligands For Asymmetric Catalysis”, RajanBabu, T. V.; Casalnuovo, A. L.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1992, 114, 6265-6266.<\/span><\/td>\n

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\n
25<\/span><\/div>\n<\/td>\n
“Stereochemistry of Intramolecular Free-Radical Cyclization Reactions”, RajanBabu, T. V.<\/span><\/p>\n
\n

Acc. Chem. Res. 1991, 24, 139-145.<\/span><\/td>\n

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\n
24<\/span><\/div>\n<\/td>\n
“Free Radical Mediated Reduction and Deoxygenation of Epoxides”, RajanBabu, T. V.; Nugent, W. A.; Beattie, M. S.,<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1990, 112, 6408-6409.<\/span><\/td>\n

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\n
23<\/span><\/div>\n<\/td>\n
“Intermolecular Addition of Epoxides to Activated Olefines: A New Reaction”, RajanBabu, T. V.; Nugent, W. A.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1989, 111, 4525-4527.<\/span><\/td>\n

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\n
22<\/span><\/div>\n<\/td>\n
“Conformational Effects on Hex-5-enyl Radical Cyclizations: From Carbohydrates to Carbocycles III”, RajanBabu, T. V.; Fukunaga, T.; Reddy, G. S.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1989, 111, 1759-1769.<\/span><\/td>\n

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\n
21<\/span><\/div>\n<\/td>\n
“Stereochemical Control in Hex-5-enyl Radical Cyclizations: Axial vs. Equatorial 2-(But-3-enyl)cyclohexyl Radicals”, RajanBabu, T. V.; Fukunaga, T.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1989, 111, 296.<\/span><\/td>\n

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\n
20<\/span><\/div>\n<\/td>\n
“Transition Metal-Centered Radicals in Organic Synthesis – Ti(III)-Induced Cyclization of Epoxyolefins”, Nugent, W. A.; RajanBabu T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1988, 110, 8561-8562.<\/span><\/td>\n

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\n
19<\/span><\/div>\n<\/td>\n
“Stereoselective Cyclization of Enynes Mediated by Metallocene Reagents”, RajanBabu, T. V.; Nugent, W. A.; Taber, D. F.; Fagan, P. J.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1988, 110, 7128-7135.<\/span><\/td>\n

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\n
18<\/span><\/div>\n<\/td>\n
“Group Transfer Polymerization With Polyunsaturated Esters and Silylpolyenolates”, Hertler, W. R.; RajanBabu T. V.: Sogah, D. Y.: Ferguson, R. C.: Ovenall, D. W.: III, Reddy, G. S.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1988, 110, 5841-5853.<\/span><\/td>\n

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\n
17<\/span><\/div>\n<\/td>\n
“From Carbohydrates to Optically Active Carbocycles, II: A Free Radical Route to Corey-Lactone From 3-Deoxyglucose”, RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 1988, 53, 4522-4530.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
16<\/span><\/div>\n<\/td>\n
“From Carbohydrates to Optically Active Carbocycles, I: Stereochemical Control in Sugar Hex-5-enyl Radical Cyclization”, RajanBabu T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1987, 109, 609-610.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
15<\/span><\/div>\n<\/td>\n
“1-Methylene Sugars as C-Glycoside Precursors”, RajanBabu, T. V.; Reddy, G. S.<\/span><\/p>\n
\n

J. Org. Chem. 1986, 51, 5458.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
14<\/span><\/div>\n<\/td>\n
“\u03b1-Nitroarylation of Ketones and Esters: An Exceptionally Facile Synthesis of Indoles, 2-Indolinones and Arylacetic Acids”, RajanBabu, T. V.; Chenard, B. L.; Petti, M. A.<\/span><\/p>\n
\n

J. Org. Chem. 1986, 51, 1704-1712.<\/span><\/td>\n

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\n
13<\/span><\/div>\n<\/td>\n
“Silylstannanes: Useful Reagents for Bis-Functionalization of \u03b1,\u03b2-Unsaturated Ketones and Acetylenes”, Chenard, B. L.; Laganis, E. D.; Davidson, F.; RajanBabu, T. V.,<\/span><\/p>\n
\n

J. Org. Chem. 1985, 50, 3666.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
12<\/span><\/div>\n<\/td>\n
“Pd(0)-Catalyzed C-Glycosylation: A Facile Alkylation of Trifluoroacetylglucal”, RajanBabu, T. V.<\/span><\/p>\n
\n

J. Org. Chem. 1985, 50, 3642-3644.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
11<\/span><\/div>\n<\/td>\n
“Nucleophilic Addition of Silyl Enol Ethers to Aromatic Nitrocompounds: Scope and Mechanism of Reaction”, RajanBabu T. V.; Reddy, G. S.; Fukunaga, T.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1985, 107, 5473-5483.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
10<\/span><\/div>\n<\/td>\n
“Nucleophilic Addition of Silyl Enol Ethers to Aromatic Nitrocompounds: A Facile Synthesis of \u03b1-Nitroaryl Carbonyl Compounds”, RajanBabu, T. V.; Fukunaga, T.<\/span><\/p>\n
\n

J. Org. Chem. 1984, 49, 4571-4572.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
9<\/span><\/div>\n<\/td>\n
“Addition of Ketene Trimethylsilyl Acetals to \u03b1,\u03b2-Unsaturated Ketones: A New Strategy for Michael Addition of Ester Enolates”, RajanBabu T. V.<\/span><\/p>\n
\n

J. Org. Chem. 1984, 49, 2083-2089.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
8<\/span><\/div>\n<\/td>\n
“Synthesis of Reactive-Ended Acrylic Polymers by Group Transfer Polymerization: Initiation with Silyl Ketene Acetals”, Webster, O. W.; Hertler, W. R.; Sogah, D. Y.; Farnham, W. B.; RajanBabu T. V.<\/span><\/p>\n
\n

J. Macromol. Sci.-Chem. 1984, A21 (8&9), 943-960.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
7<\/span><\/div>\n<\/td>\n
“Group Transfer Polymerization, 1. A New Concept for Addition Polymerization with Organosilicon Initiators”, Webster, O. W.; Hertler, W. R.; Sogah, D. Y.; Farnham, W. B.; RajanBabu T. V.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1983, 105, 5706-5707.<\/span><\/td>\n

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\n
6<\/span><\/div>\n<\/td>\n
“Chemistry of Bridged Aromatics. A Study of the Substituent Effect on the Course of Bond Cleavage of 9,10-Dihydro-9,10-ethanoanthracenes and an Oxyanion-Assisted Retro-Diels-Alder Reaction”, RajanBabu, T. V.; Eaton, D. F.; Fukunaga, T.<\/span><\/p>\n
\n

J. Org. Chem. 1983, 48, 652-657.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
5<\/span><\/div>\n<\/td>\n
“Asymmetric Total Synthesis of Erythromycin, 1. Synthesis of an Erythronolide A Seco Acid Derivative via Asymmetric Induction”, Woodward, R. B.; … RajanBabu, T. V. et al, (41 Authors)<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1981, 103, 3210-3213.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
4<\/span><\/div>\n<\/td>\n
“Asymmetric Total Synthesis of Erythromycin, 2. Synthesis of an Erythronolide A Lactone System”, Woodward, R. B.; … RajanBabu, T. V. et al, (41 Authors)<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1981, 103, 3213-3215.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
3<\/span><\/div>\n<\/td>\n
“Asymmetric Total Synthesis of Erythromycin, 3. Total Synthesis of Erythromycin”, Woodward, R. B.; … RajanBabu, T. V. et al, (41 Authors)<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1981, 103, 3215-3217.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
2<\/span><\/div>\n<\/td>\n
“Surprises in Base-Catalyzed Decompositions of Bicyclo[4.2.1]nona-2,4,7-trien-9-one Hydrazone”, RajanBabu T. V.; Sanders, D. C.; Shechter, H.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1977, 99, 6449-6450.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n
\n
1<\/span><\/div>\n<\/td>\n
“Carbenic Rearrangement and Fragmentation of Bicyclo[4.2.2]-deca-2,4,9-trien-7-ylidene and Bicyclo[4.2.1]nona-2,4,7-trien-9-ylidene”, RajanBabu, T. V.; Shechter, H.<\/span><\/p>\n
\n

J. Am. Chem. Soc. 1976, 98, 8261-8262.<\/span><\/td>\n

\"PDF\"<\/a><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"

Original Publications – All Number Title, Authors Journal, Year, Volume, Pages 104 “Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene”, Timsina, Y. T.; Biswas, S.; RajanBabu, T. V.\u00a0\u00a0\u00a0\u00a0 http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja501979g J. Am. Chem. Soc. 2014, 136, 6215-6218. … Continue reading →<\/span><\/a><\/p>\n","protected":false},"author":3,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-18","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/pages\/18","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/comments?post=18"}],"version-history":[{"count":8,"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/pages\/18\/revisions"}],"predecessor-version":[{"id":414,"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/pages\/18\/revisions\/414"}],"wp:attachment":[{"href":"https:\/\/research.cbc.osu.edu\/rajanbabu.1\/wp-json\/wp\/v2\/media?parent=18"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}