Publications

PUBLICATIONS FROM OSU

[64] Malaria Diagnosis using Paper-Based Microfluidic Device for Clinical Blood Sampling and Analysis by Portable Mass Spectrometer Suji Lee, Sierra Jackson, Kingsley Badu, and Abraham K. Badu-Tawiah* Manuscript In Preparation

[63] Panoptic Mass Spectrometry Dmytro S. Kulyk, Simon Maher, and Abraham K. Badu-Tawiah* Manuscript In Preparation

[62] Capturing Fleeting Intermediate in Claisen Rearrangement Using Non-Equilibrium Droplet Imbibition Reaction Conditions Taghi Sahraeian, Dmytro S. Kulyk, and Abraham K. Badu-Tawiah* Manuscript In Preparation

[61] The Effect of the Physical Morphology of Dried Biofluids on the Chemical Stability of Analytes Stored in Paper and Direct Analysis by Mass SpectrometryBenjamin S. Frey, Deidre E. Damon, and Abraham K. Badu-Tawiah* Analytical Chemistry, 2022 In Press

[60] Dehydration of gas-phase benzyl amine alcohols studied at atmospheric pressure Dmytro Kulyk, Qiongqiong Wan, Taghi Sahraeian, Abraham K. Badu-Tawiah* International Journal of Mass Spectrometry 2022, 476, 116836

[59] Automated Immunoassay Performed on 3D Microfluidic Paper-Based Device for Malaria Detection by Ambient Mass SpectrometrySierra Jackson, Suji Lee, Abraham K. Badu-Tawiah Analytical Chemistry, 2022, 94, 12, 5132–5139

[58] Embossed Paper Platform for Whole Blood Collection, Room Temperature Storage, and Direct Analysis by Pinhole Paper Spray Mass Spectrometry Benjamin S. Frey, Derik R. Heiss, Abraham K. Badu-Tawiah* Analytical Chemistry 2022, 94, 10, 4417–4425

[57] Reactive Thread Spray Mass Spectrometry for Localization of C=C Bonds in Free Fatty Acids: Applications for Obesity Diagnosis Devin J. Swiner, Dmytro S. Kulyk, Hannah Osae, George R. Durisek, Abraham K. Badu-Tawiah* Analytical Chemistry 2022, 94, 5, 2358–2365

[56] Ambient ion focusing for paper spray ionization Smith, B.L.; Boisdon, C.; Romero-Perez, D.; Sham, T.-T.; Bastani, B.; Zhou, Y.; McWilliam, S.; Badu-Tawiah, A.K.; Maher, S. International Journal of Mass Spectrometry 2022, 471, 116737 – 116737

[55] Enzyme-Catalyzed Hydrolysis of Lipids in Charged Microdroplets Studied by Contained-Electrospray IonizationBenjamin J. Burris and Abraham Badu-Tawiah* Analytical Chemistry, 2021, 93, 13001–13007

[54] Microsampling with Solid Phase Extraction Cartridge: Storage and Online Mass Spectrometry Analysis Dmytro S. Kulyk, Taghi Sahraeian, Suji Lee, and Abraham K. Badu-Tawiah* Analytical Chemistry, 2021, 93, 13632 –13640

[53] In-source Microdroplet Derivatization using Coaxial Contained-Electrospray Mass Spectrometry for Enhanced Sensitivity in Saccharides Analysis Derik R. Heiss and Abraham K. Badu-Tawiah* Analytical Chemistry, 2021, 93, 50, 16779–16786

[52]Protective Mechanism of Dried Blood Spheroids: Stabilization of Labile Analytes in Whole Blood, Plasma and Serum Benji S. Frey, Deidre Damon, Danyelle M. Allen, Jill Baker,  Samuel Asamoah, and Abraham K. Badu-Tawiah* Analyst, 2021, 146, 6780 – 6787

[51] Enhanced Thread Spray Mass Spectrometry: A General Method for Direct Pesticide Analysis in Various Complex MatricesSierra Jackson and Abraham K. Badu-Tawiah*  Analyst, 2021, 146, 5592 – 5600

[50] Clinical Chemistry for Developing Countries: Mass Spectrometry Suji Lee, Kavyasree Chintalapudi, and Abraham K. Badu-Tawiah* Annu. Rev. Anal. Chem. 2021, 14, 437-465

[49] Uncatalyzed N-Alkylation of Amines in Ionic Wind from Ambient Corona Discharge Suji Lee, Dmytro S. Kulyk, Nicholas Marano, and Abraham K. Badu-Tawiah* Analytical Chemistry 2021, 93, 4, 2440

[48] Monoacylation of Symmetrical Diamines in Charge Microdroplets Emelia Ansu-Gyeabourh, Enoch Amoah, Chandrashekar Ganesa, and Abraham K. Badu-Tawiah* J. Am. Soc. Mass Spectrom. 2021, 32, 2, 531–536

[47] Accelerated nucleophilic substitution reactions of dansyl chloride with aniline under ambient conditions via dual-tip reactive paper spray Norfatirah Muhamad Sarih, , , , , , , , Simon Maher* Scientific Reports 2020, 10, 21504

[46] High-Throughput Mass Spectrometry Screening Platform for Discovering New Chemical Reactions under Uncatalyzed, Solvent-Free Experimental Conditions Dmytro S. Kulyk, Enoch Amoah, and Abraham K. Badu-Tawiah* Analytical Chemistry 2020, 92, 15025–15033

[45] An Integrated Electrocatalytic nESI-MS Platform for Quantification of Fatty Acid Isomers Directly from Untreated Biofluids Kavyasree Chintalapudi and Abraham K. Badu-Tawiah* Chemical Science, 2020, 11, 9891

[44]Direct Differentiation of Whole Blood for Forensic Serology Analysis by Thread Spray Mass Spectrometry Sierra Jackson, Benjamin S. Frey, Maia N. Bates, Devin J. Swiner, and Abraham K. Badu-Tawiah*

[43] Analysis of non‑conjugated steroids in water using paper spray mass spectrometry Fred. P. M. Jjunju, Deidre E. Damon, David Romero‑Perez, Iain S. Young, Ryan J. Ward, Alan Marshall, Simon Maher* and Abraham K. Badu‑Tawiah* Scientific Reports 2020, 10, 10698

[42]Spray Mechanism of Contained-Electrospray IonizationColbert Miller, Benjamin Burris, and Abraham K. Badu-Tawiah* J. Am. Soc. Mass Spectrom. 2020, 31, 1499–1508

[41] Direct Analysis of Doping Agents in Raw Urine Using Hydrophobic Paper Spray Mass SpectrometryEduardo Luiz Rossini, Dmytro S. Kulyk, Emelia Ansu-Gyeabourh, Taghi Sahraeian, Helena Redigolo Pezza, and Abraham K. Badu-Tawiah* J. Am. Soc. Mass Spectrom. 2020, 31, 1212–1222

[40] A proof-of-concept, two-tiered approach for ricin detection using ambient mass spectrometry Devin J. Swiner, George R. Durisek III, Hannah Osae and Abraham K. Badu-Tawiah* RSC Advances, 2020, 10, 17045-17049

[39] Applications of Mass Spectrometry for Clinical Diagnostics: The Influence of Turnaround Time Devin Swiner, Sierra Jackson, Ben Burris, Abraham K. Badu-Tawiah* Analytical Chemistry, 2020, 92, 1, 183–202

[38]Novel Manufacturing Method for Producing Apohemoglobin and its Biophysical Properties Ivan S. Pires, Donald A. Belcher, Colbert Miller, Abraham K. Badu-Tawiah, Jin Baek,  Paul Buehler Andre Palmer* Biotechnology and Bioengineering, 2020, 117, 125-145

[37] Droplet Imbibition Enables Non-Equilibrium Interfacial Reactions in Charged Microdroplets Taghi Sahraeian, Dmytro S. Kulyk, and Abraham K. Badu-Tawiah* Langmuir 2019, 35, 45, 14451–14457

[36] Determining Surface Energy of Porous Substrates by Spray Ionization Deidre E. Damon, Yosef S. Maher, Danyelle M. Allen, Jill Baker, Boyce S. Chang, Simon Maher, Martin M. Thuo,  Abraham K. Badu-Tawiah* Langmuir 2019, 35, 43, 13853–13859

[35] Direct Mass Spectrometry Analysis of Complex Mixtures by Nano-Electrospray with Simultaneous Atmospheric Pressure Chemical Ionization and Electrophoretic Separation CapabilitiesDmytro S. Kulyk, Devin J Swiner, Taghi Sahraeian, Abraham K. Badu-Tawiah* Analytical Chemistry, 2019, 91(18), 11562-11568

[34] Real-time Photoreaction Screening Allows the Discovery of N-Substituted Auxiliaries as Mediators for Aerobic Dehydrogenation of Tetrahydroisoquinolines: A Theory-Guided Catalytic DesignSavithra Jayaraj and Abraham K. Badu-Tawiah* Scientific Reports 2019, 9, 11280

[33] Emerging Trends in Paper Spray Mass Spectrometry: Microsampling, Storage, Direct Analysis and Applications Benji Frey, Deidre Damon, Abraham K Badu-Tawiah* Mass Spectrometry Reviews 2019, 1-35

[32] Microsampling with Cotton Thread: Storage and Ultra-Sensitive Analysis by Thread Spray Mass Spectrometry Swiner, D. J.; Jackson, S.; Durisek, G. R.; Walsh, B. K.; Kouatli, Y.; Badu-Tawiah, A. K.* Analytica Chimica Acta 2019, 1082, 98-108

[31] Rapid Scotch Whisky Analysis and Authentication using Desorption Atmospheric Pressure Chemical Ionisation Mass Spectrometry Smith, B.L.; Hughes, D.M.; Badu-Tawiah, A.K.; Eccles, R.; Goodall, I.; Maher, S.* Scientific Reports 2019, 9, 7994

[30] Reactive Olfaction Ambient Mass Spectrometry Dmytro S. Kulyk, Taghi, Sahraeian, Qiongqiong Wan, Abraham K. Badu-Tawiah* Analytical Chemistry, 2019, 91(10), 6790

[29] Dried Blood Spheroids for Dry-state Room Temperature Stabilization of Microliter Blood Samples Deidre E. Damon, Mengzhen Yin, Christian J. Tanny, Yosef S. Maher, Stephanie Oyola-Reynoso, Barry L. Smith, Simon Maher, Martin M. Thuo, Abraham K. Badu-Tawiah* Analytical Chemistry, 2018, 90(15), 9353

[28] “An Integrated Mass Spectrometry Platform Enables Picomole-Scale Real-time Electrosynthetic Reaction Screening and DiscoveryQiongqiong Wan, Suming Chen and Abraham K. Badu-Tawiah* Chemical Science, 2018, 9, 5724

[27] Thread Spray Mass Spectrometry for Direct Analysis of Capsaicinoids in Pepper Products Sierra Jackson, Devin J. Swiner, Patricia C. Capone and Abraham K. Badu-Tawiah*  Analytica Chimica Acta, 2018, 1023, 81-88

[26] Re-configurable, Multi-mode Contained-electrospray Ionization for Protein Folding and Unfolding on Milliseconds Time Scale Colbert F. Miller, Dmytro S. Kulyk, Jongin W. Kim, and Abraham K. Badu-Tawiah*  Analyst, 2017, 142, 2152-2160

[25] Direct and Efficient Dehydrogenation of Tetrahydroquinolines and Primary Amines Using Corona Discharge Generated on Ambient Hydrophobic Paper Substrate Kathryn M Davis, Abraham K. Badu-Tawiah* J. Am Soc. Mass Spectrom., 2017, 28(4) 647–654

[24] Electrospray Soft-landing for Construction of Non-covalent Molecular Nanostructures using Charged Droplets at Ambient Condition Jian Hou, Qingna Zheng, Abraham K. Badu-Tawiah, Caiqiao Xiong, Cuizhong Guan, Suming Chen, Zongxiu Nie,* Dong Wang* and Lijun Wan* Chemical Communications 2016, 52, 13660-13663

[23] Direct Analysis and Quantification of Metaldehyde in Water using Reactive Paper Spray Mass Spectrometry Simon Mahera*, Fred P. M. Jjunju, Deidre E. Damon, Yosef S. Maher, Safaraz U. Syed, Ron M. A. Heeren, Stephen Taylor, Iain S. Young and Abraham K. Badu-Tawiah* Scientific Reports, 2016, 6 (35643), 1-10

[22] Picomole-Scale Real-Time Photoreaction Screening: Discovery of the Visible-Light-Promoted Dehydrogenation of Tetrahydroquinolines under Ambient Conditions” Suming Chen, Qiongqiong Wan and Abraham K. Badu-Tawiah*  Angew. Chem. Int. Ed. 2016, 55, 9345 –9349

[21] “2D wax-printed paper substrates with extended solvent supply capabilities allow enhanced ion signal in paper spray ionization” Deidre E. Damon, Yosef S. Maher,  M. Yin,  Fred P. M. Jjunju,  Simon Maher, Stephen Taylor, and A. K. Badu-Tawiah*  Analyst, 2016,141, 3866-3873

[20] Mass Spectrometry for Paper-based Immunoassays: Towards On-demand Diagnosis” Suming Chen, Qiongqiong Wan, Abraham Badu-Tawiah* J. Am. Chem. Soc. 2016, 138 , 6356–6359

[19] Direct Biofluid Analysis using Hydrophobic Paper Spray Mass Spectrometry Deidre E. Damon, Kathryn M. Davis, Camila R. Moreira, Patricia Capone, Riley Cruttenden, and Abraham K. Badu-Tawiah* Anal. Chem. 2016, 88, 1878–1884

[18] Screening and Quantification of Aliphatic Primary Alkyl Corrosion Inhibitor Amines in Water Samples by Paper Spray Mass SpectrometryFred P. M. Jjunju, Simon Maher, Deidre E. Damon, Dick. R. Barrett, S. U. Syed, R. M. A. Heere, Stephen Taylor *, Abraham .K. Badu-Tawiah,* Anal. Chem. 2015, 88, 1391–1400

[17] Reactive charged droplets for reduction of matrix effects in electrospray ionization mass spectrometry Dmytro S. Kulyk, Colbert F. Miller, and Abraham K. Badu-Tawiah* Anal. Chem. 2015, 87(21), 10988–10994

[16] In-situ Bio-conjugation and Ambient Surface Modification using Reactive Charged Droplets He, Q.; Badu-Tawiah, A.K.*; Chen, S.; Xiong, C.; Liu, H.; Zhou, Y.; Hou, J.; Zhang, N.; Li, Y.; Xie, X.; Wang, J.; Mao, L.; Nie, Z.*  Anal. Chem. 2015, 87 (6), 3144–3148

[15] Mass Spectrometry Imaging Reveals the Sub-organ Distribution of Carbon Nanomaterials Chen, S.; Xiong, C.; Liu, H.; Wan, Q.; Hou, J.; Wang, J.; He, Q.; Badu-Tawiah, A.; Nie, Z.* Nature Nanotechnology, 2015, 10, 176-182

[14] Analysis of Polycyclic Aromatic Hydrocarbons Using Desorption Atmospheric Pressure Chemical Ionization Coupled to a Portable Mass Spectrometer Jjunju, F.P.M.; Maher, S.; Li, A.; Badu-Tawiah, K.; Taylor*, S.; Cooks, R.G.*   J. Am. Soc. Mass Spectrom. 2015, 26, 271-280

PRIOR TO OSU

[13] Polymerization-based signal amplification for paper-based immunoassays Badu-Tawiah, K.; Lathwal, S.; Kaastrup, K.; Al-Sayah, M.; Christodouleas, D.C.; Smith, B.S.; Whitesides, M.G.*; Sikes, D.H.*  Lab Chip, 2015, 15, 655-659

[12]  Chemical aspects of the extractive methods of ambient ionization mass spectrometry Abraham K. Badu-Tawiah, Livia S Eberlin, Zheng Ouyang, and R Graham Cooks Annu. Rev. Phys. Chem.2013, 64, 481-505

[11]   In situ analysis of corrosion inhibitors using a portable mass spectrometer with paper spray ionization Fred PM Jjunju, Anyin Li, Abraham Badu-Tawiah, Pu Wei, Linfan Li, Zheng Ouyang, Iman S Roqan, R Graham Cooks Analyst 2013, 3740-3748

[10]   Hydrocarbon analysis using desorption atmospheric pressure chemical ionization Fred PM Jjunju, Abraham K Badu-Tawiah, Anyin Li, Santosh Soparawalla, Iman S Roqan, R Graham Cooks Int. J. Mass Spectrom. 2013, 345, 80-88

[9]  Peptide Cross‐Linking at Ambient Surfaces by Reactions of Nanosprayed Molecular Cations Abraham K. Badu‐Tawiah, Anyin Li, Fred PM Jjunju, and R Graham Cooks Angew. Chem. Int. Ed. 2012, 51, 9417–9421

[8]  Accelerated Carbon-Carbon Bond‐Forming Reactions in Preparative Electrospray Thomas Müller, Abraham Badu‐Tawiah, R Graham Cooks Angew. Chem. Int. Ed. 2012, 51, 11832 –11835

[7]   Accelerated C–N bond formation in dropcast thin films on ambient surfaces Abraham K Badu-Tawiah, Dahlia I Campbell, R Graham Cooks J. Am. Soc. Mass Spectrom. 2012, 23,1461-1468

[6]   Reactions of microsolvated organic compounds at ambient surfaces: Droplet velocity, charge state, and solvent effects Abraham K Badu-Tawiah, Dahlia I Campbell, R Graham Cooks J. Am. Soc. Mass Spectrom. 2012, 23,1077-1084

[5]   Reactions of organic ions at ambient surfaces in a solvent-free environment Abraham K Badu-Tawiah, Jobin Cyriac, R Graham Cooks J. Am. Soc. Mass Spectrom. 2012, 23, 842-849

[4]   Ambient ion soft landing Abraham K Badu-Tawiah, Chunping Wu, R Graham Cooks Anal. Chem. 2011, 83 (7), 2648-2654

[3]   Analysis and modification of surfaces using molecular ions in the ambient environment Ryan D Espy, Abraham Badu-Tawiah, R Graham Cooks Current Opinion in Chemical Biology, 2011, 15, 1-7

[2]  Enhanced ion signals in desorption electrospray ionization using surfactant spray solutions Abraham Badu-Tawiah, R Graham Cooks J. Am. Soc. Mass Spectrom. 2010, 21, 1423-1431

[1]  Non-aqueous spray solvents and solubility effects in desorption electrospray ionization Abraham Badu-Tawiah, Celine Bland, Dahlia I Campbell, R Graham Cooks J. Am. Soc. Mass Spectrom. 2010 , 21, 572-579